Vol. 33, issue 08, article # 1

Abstract:

A universal function is suggested for calculation of the A-broadening coefficients g of H₂S absorption lines (A = He, Ne, Ar, Kr, and Xe). Only one parameter of this function depends on the broadening gas atom, while other parameters are common for all atoms. This parameter determines the ratio ν(А)/ν(А´) for A and A´ atoms. Parameters of the function are determined in the fitting procedure from the coefficients γ measured and calculated for ν₁, ν₂, and ν₃ vibrational bands of H₂S molecules. The coefficients g calculated are statistically compared with measurements. With the exception of some data for the ν₁ and ν₃ bands, the calculated and measured γ are in a good agreement for all collisional partners A.

Keywords:

hudrogen sulphide, noble gas broadening, analytical model

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