The ingress of carbon into the snow cover with ions of organic carboxylic acids (formic (formate), acetic (acetate), and oxalic (oxalate)) in the permafrost landscapes of Eastern Siberia is studied. The content of ions of organic carboxylic acids is estimated in areas with the latitude-zonal and mountain-belt type of permafrost landscapes. The maximal content is observed in middle-taiga landscapes. The density of ingress of ions of organic carboxylic acids in snow of permafrost landscapes is subject to altitudinal zonation and follows a decrease in the total mass of plants, which are the main source of organic carboxylic acids in the atmosphere. In the middle-taiga landscapes, organic carboxylic acids can have a significant effect on the ingress of carbon with precipitation. In all mountain-belt types of permafrost landscapes, the bulk of carbon comes from carbonates (bicarbonates), and the role of organic carboxylic acids in the ingress of carbon into snow is insignificant and sharply decreases with an increase in altitude.
Siberia, permafrost landscapes, snow, organic carboxylic acids (formic, acetic, oxalic), migration
1. Varshal G.M., Koshcheeva I.Ya., Sirotkina I.S., Velyuhanova T.K., Intskirveli L.G., Zamokina N.S. Izuchenie organicheskih veshchestv poverhnostnyh vod i ih vzaimodejstviya s ionami metallov v svyazi s migratsiej zagryaznyayushchih veshchestv v ob"ektah vneshnej sredy // Organicheskaya geohimiya vod i poiskovaya geohimiya. Materialy VIII Mezhdunar. kongressa po organ. geohimii. M.: Nauka, 1982. P. 202–212.
2. Uspenskaya A.I., Galeev A.A. Rol' shchavelevoj kisloty v global'nom tsikle ugleroda // Neft'. Gaz. Novatsii. 2009. N 10 (129). P. 8–10.
3. Keene W.C., Galloway J.N. The biogeochemical cycling of formic and acetic acids through the troposphere: An overview of current understanding // Tellus. B. 1988. V. 40. Р. 322–334.
4. Touré P.R., Kouadio G.K., Koffi U.K., Beugré C.R. Study of formic and acetic acids in the air of humid savannah case of Lamto (Cote d’Ivoire) // Atmos. Clim. Sci. 2016. N 6. P. 254–266.
5. .N. Geohimiya snezhnogo pokrova taezhnyh i gornyh merzlotnyh landshaftov Yakutii // Led i sneg. 2014. N 1 (125). P. 73–80.
6. Vasilenko V.N., Nazarov I.M., Fridman Sh.D. Monitoring zagryazneniya snezhnogo pokrova. L.: Gidrometeoizdat, 1985. 182 p.
7. Fedorov A.N., Botulu T.A., Varlamov S.P., Vasil'ev I.S., Gribanova S.P., Dorofeev I.V., Klimovskij I.V., Samsonova V.V., Solov'ev P.A. Merzlotnye landshafty YAkutii (Poyasnitel'naya zapiska k «Merzlotno-landshaftnoj karte Yakutskoj ASSR» masshtaba 1:2 500 000). Novosibirsk: GUGK, 1989. 170 p.
8. Bazilevich N.I., Grebennikov O.S., Tishkov A.A. Geograficheskie aspekty zakonomernosti struktury i funktsionirovaniya ekosistem. M.: Nauka, 1986. 297 p.
9. Molozhnikov V.N., Pautova V.N., Pletnikova T.A. Fitomassa i produktivnost' kedrovogo stlanika // Pochvy i rastitel'nost' merzlotnyh rajonov SSSR. 1973. P. 301–303.
10. Pozdnyakov L.K., Protopopov V.V., Gorbatenko V.M. Biologicheskaya produktivnost' lesov Srednej Sibiri v Yakutii. Krasnoyarsk: Kn. izd-vo, 1969. 155 p.
11. Makarov V.N. Iony organicheskih karbonovyh kislot (formiat, atsetat i oksalat) v snezhnom pokrove merzlotnyh landshaftov boreal'noj zony Vostochnoj Sibiri // Geohimiya. 2018. N 6. P. 594–602.
12. Keene W.C., Galloway J.N. Considerations regarding sources for formic and acedic acids in the troposphere // J. Geophys. Res. 1986. N 91. P. 14466–14474.