Abstract:
It is represented the scheme of work and numerical modeling of a photoacoustic gas analyzer with IR-source and 1-st order interference filter for carbon isotope ratios analysis. An optimal spectral range for gaz analyzer operation is selected. In the selected wavelength range, the spectral characteristics of the atmosphere and some additional gazes are analyzed, which could affect the measurement results. The proposed gas analyzer allows us to measure carbon isotope ratios 13С/12С in CO2 samples with a minimal error of about 0.5‰, and could be useful for detection of such gases as SO2, CO, NH3, absorption lines of which exist in the selected spectral range.
Keywords:
gas analysis, carbon isotope ratios, photoacoustic detector, absorbtion spectrum, Fabry–Perot interferometer
References:
- Ageev B.G., Zotikova A.P., Padalko N.L., Ponomarjov Ju.N., Savchuk D.A., Sapozhnikova V.A., Chernikov E.V. Variacii soderzhanija vody, CO2 i izotopnogo sostava ugleroda CO2 v godichnyh kol'cah kedra sibirskogo // Optika atmosf. i okeana. 2011. V. 24, N 2. P. 149–154.
- Erdélyi M., Richter D., Tittel F.K. 13CO2/12CO2 isotopic ratio measurements using a difference frequency-based sensor operating at 4.35 mm // Appl. Phys. B. 2002. V. 75, N 2–3. P. 289–295.
- Modak A.S. Stable isotope breath tests in clinical medicine: A review // J. Breath Res. 2007. V. 1, N 1. P. R1–R13.
- Stepanov E.V. Laser analysis of the 13C/12C isotope ratio in CO2 in exhaled air // Quantum Electron. 2002. V. 32, N 11. P. 981–986.
- Gagliardi G., Castrillo A., Iannone R.Q., Kerstel E.R.T., Gianfrani L. High-precision determination of the 13CO2/12CO2 isotope ratio using a portable 2.008-mm diode-laser spectrometer // Appl. Phys. B. 2003. V. 77, N 1. P. 119–124.
- Stepanov E.V., Glushko A.N., Kasoev S.G., Koval' A.V., Lapshin D.A. Lazernyj spektrofotometr blizhnego IK-diapazona dlja sravnitel'nogo analiza izotopicheskogo soderzhanija CO2 v probah vydyhaemogo vozduha // Quantum Electron. 2011. V. 41, N 12. P. 1124–1130.
- Meier-Augenstein W. Applied gas chromatography coupled to isotope ratio mass spectrometry // J. Chromatog. A. 1999. V. 842, N 1–2. P. 351–371.
- Osipov K.Ju., Kapitanov V.A. Modelirovanie optiko-akusticheskogo analizatora SF6 v atmosfernom vozduhe s chastotnoj moduljaciej izluchenija teplovogo istochnika // Optika atmosf. i okeana. 2012. V. 25, N 9. P. 810–814.
- LumaScence Technologies. SF6 Leak Detector 3434i. URL: http: // www.lumasenseinc.com / EN/products/gas-monitoring/gas-monitoring-instruments/sf6-leak-detector. html
- Rothman L.S., Gordon I.E., Babikov Y., Barbe A., Benner D.C., Bernath P.F., Birk M., Bizzocchi L., Boudon V., Brown L.R., Campargue A., Chance K., Cohen E.A., Coudert L.H., Devi V.M., Drouin B.J., Fayt A., Flaud J.-M., Gamache R.R., Harrison J.J., Hartmann J.M., Hill C., Hodges J.T., Jacquemart D., Jolly A., Lamouroux J., Le Roy R.J., Li G., Long D.A., Lyulin O.M., Mackie C.J., Massie S.T., Mikhailenko S., Muller H.S.P., Naumenko O.V., Nikitin A.V., Orphal J., Perevalov V., Perrin A., Polovtseva E.R., Richard C., Smith M.A.H., Starikova E., Sung K., Tashkun S., Tennyson J., Toon G.C., Tyuterev Vl.G., Wagner G. The HITRAN 2012 molecular spectroscopic database // J. Quant. Spectrosc. Radiat. Transfer. 2013. V. 130. P. 4–50.
- Nikiforova O.Ju., Ponomarjov Ju.N., Karapuzikov A.I. Uchet vlazhnosti proby vydyhaemogo vozduha pri detektirovanii gazov-biomarkerov // Optika atmosf. i okeana. 2013. V. 26, N 4. P. 336–341.
- Electro optical components, inc. Infrared Optical Filters. IR Interference Filters: 1.5–20 mm. URL: http://www. eoc-inc.com/noc/angular_shift.htm
- Zeninari V., Kapitanov V.A., Ponomarjov Ju.N., Kurtua D. Rezonansnaja fotoakusticheskaja jachejka Gel'mgol'ca dlja spektroskopii slabo pogloshhajushhih gazov i gazoanaliza // Optika atmosf. i okeana. 1999. V. 12, N 10. P. 968–980.
- Song K., Cha H.K., Kapitanov V.A., Ponomarev Yu.N., Rostov A.P., Courtois D., Parvitte B., Zeninari V. Differential Helmholtz resonant photoacoustic cell for spectroscopy and gas analysis with room-temperature diode lasers // Appl. Phys. B. 2002. V. 75, N 2–3. P. 215–227.
- Kurth S., Hiller K., Neumann N., Heinze M., Doetzel W., Gessner T. Tunable Fabry–Perot Interferometer for 3–5 mm wavelength with bulk micromachined reflector carrier // Proc. SPIE 4983, MOEMS and Miniaturized Systems III, 215 (January 21, 2003). P. 215–226.
- Max J.A.L., Audaire L. et al. Méthodes et techniques de traitement du signal et applications aux mesures physiques / par J. Max; avec la collab. de L. Audaire. [et al.]. Masson, Paris, New York: Masson, 1981.