OPTIKA ATMOSFERY I OKEANA JOURNAL
V.E. ZUEV INSTITUTE OF ATMOSPHERIC OPTICS
Vol. 14, issue 12, article # 1
pdf Zvereva N. A., Nabiev Sh. Sh., Nadezhdinskii A. I., Ponomarev Yu. N., Stavrovskii D. B., Chernin S. M., Shubenkina T. A. IR spectra of HF and its complexes with water under atmospheric conditions. // Atmospheric and oceanic optics. 2001. V. 14. No. 12. P. 1009-1011.Copy the reference to clipboard
Abstract:
IR spectra of H2O-HF mixture have been recorded in the spectral region from 700 to 4000 cm-1 using a VECTOR-22 Fourier transform spectrometer. Analysis of the spectroscopic data enabled us to reveal some peculiarities in the spectra, in particular, a larger number of bands are observed as compared to that known from literature data. Based on ab initio quantum chemical calculations, experimental vibrational frequencies have been tentatively assigned. Our experiments show that in the atmosphere H2O and HF form various complexes.